Air Pollution, Aerosols and Clouds in the Climate System

In most climate and radiative transfer models, optical properties of aerosols are modeled using spherical shape assumptions. This assumption is based on sound scientific reasoning. All liquid aerosols have spherical shape because of surface tension. Solid aerosols, which are water soluble also eventually absorbs water vapor from atmosphere and transform themselves into spherical shape. However, dust aerosols are neither liquid nor water soluble. Soot aerosols also fall in this category. Hence, they may not necessarily have spherical shape. This requires that we should examine the validity of spherical shape assumption, particularly for these two types of aerosols. There are two aspects to look at for importance of spherical shape assumption. One is relative magnitude of non-spherical aerosol number concentration. If there are not quite large number of non-spherical particles in the atmosphere, then we need not worry about it. Li and Osada (2007) have shown using model study that dust ...

It is widely know that dust is essentially non-spherical and hence radiative transfer calculations treating dust as a spherical particle are not adequate. A recent laboratory based study on dust particles by Jingmin Li and Kazuo Osada is very interesting. This article appeared in GRL this month. They study the preferential setting of elongated mineral dust collected from snow in a high mountain in Japan. The positions of particles' centers of gravity and folding centers are analyzed using a scanning electron microscopy and optical microscopy. Their results suggest that a preferential orientation exists for particles settling heavy side down (as expected) but what is interesting is the analysis of results from Ginoux's model wherein they apply this preferential orientation information and show that : " away from the source regions, dust particles are essentially spherical, which considerably simplify the calculation of settling velocity in transport and of radiative trans...

This interesting paper appeared in ACPD on June 4 and abstract reads : This work will present aerosol size distributions measured in a Saharan dust plume between 0.9 and 12 km altitude during the ACE-2 campaign 1997. The distributions contain a significant fraction of large particles of diameters from 4 to 30 μm. Radiative transfer calculations have been performed using these data as input. Shortwave, longwave as well as total atmospheric radiative effects (AREs) of the dust plume are investigated over ocean and desert within the scope of sensitivity studies considering varied input parameters like solar zenith angle, scaled total dust optical depth, tropospheric standard aerosol profiles and particle complex refractive index. The results indicate that the large particle fraction has a predominant impact on the optical properties of the dust. A single scattering albedo of ωo=0.75–0.96 at 550 nm was simulated in the entire dust column as well as 0.76 within the Saharan dust layer at ~4 ...